A polyphenylene support for Pd catalysts with exceptional catalytic activity.
نویسندگان
چکیده
We describe a solid polyphenylene support that serves as an excellent platform for metal-catalyzed reactions that are normally carried out under homogeneous conditions. The catalyst is synthesized by palladium-catalyzed Suzuki coupling which directly results in formation of palladium nanoparticles confined to a porous polyphenylene network. The composite solid is in turn highly active for further Suzuki coupling reactions, including non-activated substrates that are challenging even for molecular catalysts.
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ورودعنوان ژورنال:
- Angewandte Chemie
دوره 53 33 شماره
صفحات -
تاریخ انتشار 2014